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Uranium(V)−imido−iodide complexes have been prepared by chemical oxidation of the corresponding uranium(IV)−imido complexes with copper(I) iodide. These U(V) organometallic systems show reversible UV/UIV and UVI/UV redox behavior in addition to classic 5f1 spectroscopic signatures. The generality of this Cu(I)-based oxidation protocol is demonstrated by preparation of the analogous U(V)−imido−triflate and −thiolate complexes using CuOTf and CuSPh, respectively.
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Graves et al. (2007) studied this question.
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