Atomically Flat, Large‐Sized, Two‐Dimensional Organic Nanocrystals

Large-sized, 2D single crystals of perylene are grown by both solution-cast and physical vapor transport methods. The crystals have a atomically flat parallelogram morphology and the aspect ratios of the lateral extension compared to the thickness are up to 103. The atomically flat feature leads to good interface contact, making a single-crystal field-effect transistor with higher mobility. The mobility of atomically flat crystals can be 103–104 times higher than rough crystals. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.