Tripodal Tris(aryl)alkoxide Ligand in Tuning Single-Molecule Magnetism of Dy³⁺ Complexes

Alexander A. Trifonov; Gautier Félix; E. V. Balagurova; Julia Larionova; Alexander N. Selikhov; Max Kallio; Veacheslav Vieru; Anna V Vologzhanina; Yannick Guari

doi:10.1039/d5dt02861b

January 1, 2026Dalton Transactions

Tripodal Tris(aryl)alkoxide Ligand in Tuning Single-Molecule Magnetism of Dy³⁺ Complexes

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Key Points

This research aims to explore how a specific ligand affects the magnetic properties of Dy³⁺ complexes.
Synthesis of Dy³⁺ complexes using tripodal tris(aryl)alkoxide ligands.
Structural analysis of the resulting complexes to determine geometry.
Assessment of magnetic properties through experimental measurements.
The complex [κ³-O,N,N-(Me₂NCH₂-o-C₆H₄)₃CO]DyCl₂(THF) displays distorted octahedral geometry.
The ligands significantly impact the magnetism of the Dy³⁺ complexes, enhancing single-molecule magnet behavior.

Implication

Investigates the magnetic properties of Dy³⁺ complexes, suggesting potential applications in magnetism.

Abstract

We report the synthesis, structures, and magnetic properties of two Dy³⁺ complexes supported by the tripodal tris(aryl)alkoxide ligand (Me₂NCH₂-o-C₆H₄)₃CO⁻. The mononuclear complex [κ³-O,N,N-(Me₂NCH₂-o-C₆H₄)₃CO]DyCl₂(THF) (1) adopts a distorted octahedral geometry, while...

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Cite This Study

Trifonov et al. (2026) studied this question.

synapsesocial.com/papers/6a0809d7a487c87a6a40ba4a https://doi.org/10.1039/d5dt02861b

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Tripodal Tris(aryl)alkoxide Ligand in Tuning Single-Molecule Magnetism of Dy³⁺ Complexes

Key Points

Implication

Abstract

Discussion

Cite This Study

Tripodal Tris(aryl)alkoxide Ligand in Tuning Single-Molecule Magnetism of Dy³⁺ Complexes

Key Points

Implication

Abstract

Discussion

Cite This Study

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