In situ X-ray absorption and emission spectroscopy to understand the electron transfer-oxygen transfer reaction of vanadium polyoxomolybdate in homogeneous medium

Kamar Bendehiba; Santanu Sarmah; Estelle Pujol; Dominique Nkeuya; Dominik Neukum; Vera Truttmann; Dmitry E. Doronkin; Nuria Romero; Philippe Serp; Jan-Dierk Grunwaldt; Bidyut Bikash Sarma

doi:10.1039/d6sc02170k

January 1, 2026Chemical ScienceOpen Access

In situ X-ray absorption and emission spectroscopy to understand the electron transfer-oxygen transfer reaction of vanadium polyoxomolybdate in homogeneous medium

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Key Points

This research aims to explore the mechanisms of electron transfer and oxygen transfer reactions in vanadium polyoxomolybdate.
Utilized in situ X-ray absorption and emission spectroscopy techniques.
Analyzed the catalyzed oxidation of xanthene and biomass-derived compounds.
Conducted experiments at room temperature.
Demonstrated stable formation of products during electron transfer reactions.
Observed significant efficiency in the oxidation of xanthene.
Highlighted the potential for biomass-derived compounds to undergo similar reactions.

Implication

Investigates electron and oxygen transfer reactions in biomass-derived compounds, suggesting catalyst efficiency.

Abstract

Electron transfer-oxygen transfer reactions of vanadium polyoxomolybdates have been investigated in the homogeneously catalysed oxidation of xanthene and biomass-derived compounds. At room temperature, we observed the formation of a stable...

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Cite This Study

Bendehiba et al. (2026) studied this question.

synapsesocial.com/papers/6a080a9fa487c87a6a40c849 https://doi.org/10.1039/d6sc02170k

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In situ X-ray absorption and emission spectroscopy to understand the electron transfer-oxygen transfer reaction of vanadium polyoxomolybdate in homogeneous medium

Key Points

Implication

Abstract

Discussion

Cite This Study

In situ X-ray absorption and emission spectroscopy to understand the electron transfer-oxygen transfer reaction of vanadium polyoxomolybdate in homogeneous medium

Key Points

Implication

Abstract

Discussion

Cite This Study

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