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Reflectivity spectra of ZnTe and ZnSe are studied experimentally and theoretically. The measurements are made at 15 and 300^, and the theoretical calculations are done at an assumed temperature of 300^. Spin-orbit interactions are included in the empirical pseudopotential calculation of the electronic band structures for both ZnTe and ZnSe. The imaginary part of the frequency-dependent dielectric function, the reflectivity, and the derivative of the reflectivity are calculated. In addition, a direct comparison of the measured and calculated reflectivity is made. The calculated derivative of the reflectivity is compared with thermo-reflectance data. The electronic transitions causing the reflectivity peaks are identified.
Walter et al. (Sun,) studied this question.