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April 4, 2012Annual Review of Physical Chemistry577 citations

Relativistic Effects in Chemistry: More Common Than You Thought

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PPPekka Pyykkö

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Abstract

Relativistic effects can strongly influence the chemical and physical properties of heavy elements and their compounds. This influence has been noted in inorganic chemistry textbooks for a couple of decades. This review provides both traditional and new examples of these effects, including the special properties of gold, lead-acid and mercury batteries, the shapes of gold and thallium clusters, heavy-atom shifts in NMR, topological insulators, and certain specific heats.

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Pekka Pyykkö (2012) studied this question.

synapsesocial.com/papers/6a084a7f113ba5b476de1390https://doi.org/10.1146/annurev-physchem-032511-143755
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