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A low molecular weight gelator (LMWG) containing both anion- and metal-binding functionalities forms gels in methanol in the presence of CuBr2. Shear in the form of short shaking rather than sonication transforms the system from a weak jelly like aggregate into a robust gel, exhibiting clear structural changes of the gel fibres by SEM. Reversible anion tuning with tetrabutylammonium acetate and Cu(BF4)2 allows these compounds to act as anion responsive soft materials.
Piepenbrock et al. (Fri,) studied this question.
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