The use of organic and inorganic compounds belonging to the class of peroxides in the initiation of addition polymerization is well known. It has been found that the addition of small amounts of additives brings about the initiation of the polymerization of vinyl monomers with ease. Such polymerizations have been termed reduction-oxidation or redox. An example of such a reaction is the formation of hydroxy free radicals in the well-known reaction
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Misra et al. (1984) studied this question.
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