Aluminium-Catalysed Carbonyl-Selective Hydrophosphinylation of α,β-Unsaturated Ketones

Ziyuan Pang; Wen Dai; Xiaobo Yang; Xiaoli Ma; Hongping Zhu; Zhi Yang

doi:10.1039/d6qo00397d

January 1, 2026Organic Chemistry Frontiers

Aluminium-Catalysed Carbonyl-Selective Hydrophosphinylation of α,β-Unsaturated Ketones

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Key Points

To investigate the catalytic performance of aluminium hydride complexes in the hydrophosphinylation of α,β-unsaturated ketones.
Synthesized Schiff-base-supported non-precious metal complexes.
Assessed the catalytic activity of the aluminium hydride complex C1 under various conditions.
Aluminium hydride complex C1 demonstrated exceptional catalytic activity compared to other non-precious metal complexes.
Significant improvement in carbonyl-selective hydrophosphinylation was achieved using this complex.

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Implication

Evaluates catalytic activity of aluminium hydride complex in α,β-unsaturated ketones, indicating promising applications in organic synthesis.

Abstract

An aluminium-catalysed carbonyl-selective hydrophosphinylation of α,β-unsaturated ketones is reported herein. Among the synthesised Schiff-base-supported non-precious metal complexes, the aluminium hydride complex C1 exhibited outstanding catalytic activity. In contrast to conventional...

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Pang et al. (2026) studied this question.

synapsesocial.com/papers/6a095b8e7880e6d24efe14f5 https://doi.org/10.1039/d6qo00397d

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Aluminium-Catalysed Carbonyl-Selective Hydrophosphinylation of α,β-Unsaturated Ketones

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

Aluminium-Catalysed Carbonyl-Selective Hydrophosphinylation of α,β-Unsaturated Ketones

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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