Activation by light: Caged depsipeptides are incorporated as photoresponsive elements into the backbone of the protein SDF-1α by using expressed protein ligation. The disturbed secondary structure is restored after UV treatment by an O→N acyl rearrangement, and the chemotactic potential of the protein is regained. Nvoc=6-nitroveratryloxycarbonyl.
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Baumann et al. (2013) studied this question.
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