Ice is born in low-mobility regions of supercooled liquid water

Significance From intracellular freezing to cloud formation, the crystallization of water is ubiquitous and shapes life as we know it. A full comprehension of the ice nucleation process at the molecular scale remains elusive and we cannot predict where nucleation will occur. Using computational techniques we show that homogeneous nucleation in supercooled water happens in immobile liquid regions that emerge from heterogeneous dynamics. With this we link the topics of nucleation and dynamical heterogeneity and open ways to understand and control heterogeneous nucleation in solution, in confinement, or at interfaces via understanding their effects on liquid dynamics.