The formation of extremely high aspect ratio CdSe nanorods (30:1), as well as arrow-, teardrop-, tetrapod-, and branched tetrapod-shaped nanocrystals of CdSe, has been achieved by growth of the nanoparticles in a mixture of hexylphosphonic acid and trioctylphosphine oxide. The most influential factors in shape control are the ratio of surfactants, injection volume, and time-dependent monomer concentration.
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Manna et al. (2000) studied this question.
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