Interfaces and Interfacial Layers in Inorganic Perovskite Solar Cells

Abstract Owing to their superior thermal stability, metal halide inorganic perovskite materials continue to attract interest for photovoltaics applications. The highest reported power conversion efficiency (PCE) for solar cells based on inorganic perovskites is over 20 %. As this PCE corresponds to 73 % of the theoretical limit, there remains more room for further improving the device PCEs than for improving organic–inorganic hybrid perovskite solar cells (PSCs). The main loss is in the photovoltage, which is limited by interfaces in terms of non‐radiative recombination caused by traps and energy‐level mismatch. Furthermore, inefficient charge extraction at interfacial contacts reduces the photocurrent and fill factor. This Minireview summarizes the recent developments in the fundamental understanding of how the interfaces and interfacial layers influence the performance of solar cells based on inorganic perovskite absorbers. An outlook for the development of highly efficient and stable inorganic PSCs from the interface point of view is also given.