Metal–Organic Framework Node-Supported Single-Site Iron(III)-Hydroxyl Catalyst for Regioselective Hydroxylation of Arenes

Rahul Kalita; Astha Pathak; Poorvi Gupta; Shilpi Sarmah; Aditya Kumar; Biplab Ghosh; Yukti Monga; Kuntal Manna

doi:10.1021/acs.inorgchem.6c01585

May 17, 2026Inorganic Chemistry

Metal–Organic Framework Node-Supported Single-Site Iron(III)-Hydroxyl Catalyst for Regioselective Hydroxylation of Arenes

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Key Points

The research aims to explore the potential of iron(III)-hydroxyl catalysts for the regioselective hydroxylation of arenes.
Utilized metal-organic frameworks to support single-site iron catalysts.
Focused on the regioselective hydroxylation process of benzene derivatives.
Demonstrated effective hydroxylation of arenes using the MOF-supported catalyst.
Showed potential for developing earth-abundant metal catalysts for fine chemical synthesis.

Implication

Demonstrates the effectiveness of a metal-organic framework-supported catalyst in hydroxylating arenes, suggesting advancements in fine chemical synthesis.

Abstract

, serve as the key species for benzene hydroxylation. This study demonstrates the utility of MOF-supported single-site earth-abundant metal catalysts for the synthesis of fine chemicals.

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Cite This Study

Kalita et al. (2026) studied this question.

synapsesocial.com/papers/6a0d5089f03e14405aa9c714 https://doi.org/10.1021/acs.inorgchem.6c01585

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Metal–Organic Framework Node-Supported Single-Site Iron(III)-Hydroxyl Catalyst for Regioselective Hydroxylation of Arenes

Key Points

Implication

Abstract

Discussion

Cite This Study

Metal–Organic Framework Node-Supported Single-Site Iron(III)-Hydroxyl Catalyst for Regioselective Hydroxylation of Arenes

Key Points

Implication

Abstract

Discussion

Cite This Study

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