May 21, 2005Open Access
View Full PaperCobalt-Catalyzed Hydroazidation of Olefins: Convenient Access to Alkyl Azides
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Abstract
Conversion of olefins to azides was achieved with high Markovnikov selectivity for a broad range of alkenes using 6 mol % Co(BF4).6H2O and ligand 1, with 3 equiv of TsN3 as nitrogen source and simple silanes (PhSiH3, TMDSO).