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The progress of transition metal-catalyzed carbochalcogenation of alkynes, which can be performed by using readily available catalysts, is reviewed. It has been proposed that stereo- and regioselective insertion of alkynes into the metal complexes is involved in the catalytic cycles. These reactions clearly demonstrate the synthetic versatility of organochalcogen compounds in transition metal-catalyzed reactions.
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Kuniyasu et al. (2006) studied this question.
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