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March 9, 2001Science5,822 citations

Nanobelts of Semiconducting Oxides

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ZPZhengwei PanZDZ. R. DaiZWZhong Lin Wang

Key Points

  • Synthesize and structurally characterize ultralong, ribbon-like nanobelts across diverse semiconducting metal oxides.
  • Evaporated commercial metal oxide powders of zinc, tin, indium, cadmium, and gallium at high temperatures without catalysts.
  • Synthesized pure, defect-free, single-crystalline oxide nanobelts with rectangular cross sections, widths of 30 to 300 nm, width-to-thickness ratios of 5 to 10, and lengths up to several millimeters.
  • Demonstrated that ribbon-like nanobelt morphology is a universal structural characteristic across oxide families spanning varied cation valence states and crystallographic structures.

Abstract

Ultralong beltlike (or ribbonlike) nanostructures (so-called nanobelts) were successfully synthesized for semiconducting oxides of zinc, tin, indium, cadmium, and gallium by simply evaporating the desired commercial metal oxide powders at high temperatures. The as-synthesized oxide nanobelts are pure, structurally uniform, and single crystalline, and most of them are free from defects and dislocations. They have a rectanglelike cross section with typical widths of 30 to 300 nanometers, width-to-thickness ratios of 5 to 10, and lengths of up to a few millimeters. The beltlike morphology appears to be a distinctive and common structural characteristic for the family of semiconducting oxides with cations of different valence states and materials of distinct crystallographic structures. The nanobelts could be an ideal system for fully understanding dimensionally confined transport phenomena in functional oxides and building functional devices along individual nanobelts.

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Cite This Study

Pan et al. (2001) studied this question.

synapsesocial.com/papers/6a0e5c27a7f61df77cc84351https://doi.org/10.1126/science.1058120
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