A bi-catalytic system, in which Ru-MACHO-BH and Ru(H)2(dppe)2 interact in a synergistic manner, was developed for the base-free dehydrogenation of methanol. A total TON > 4200 was obtained with only trace amounts of CO contamination (<8 ppm) in the produced gas.
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Monney et al. (2013) studied this question.
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