Rate constants and activation energies are calculated for D+H2→DH+H over the temperature range 444–2400 K by trajectory calculations and over the temperature range 300–2400 K by improved canonical variatonal theory with small-curvature-approximation semiclassical adiabatic ground-state transmission coefficients. Both calculations use the most accurate available potential energy surface. The results are compared to each other results for this system and for H+H2μH2+H.
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Blais et al. (1982) studied this question.
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