We have synthesized sub-10 nm Pd cubic and octahedral nanocrystals and then evaluated their activities towards oxygen reduction reaction (ORR). The ORR activity of Pd nanocubes was one order of magnitude higher than that of Pd octahedra, and comparable to that of the state-of-the-art Pt catalysts.
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Shao et al. (2011) studied this question.
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