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January 1, 1999Journal of Materials Chemistry

Structural and electrical properties of bis(ethylenedithio)tetrathiafulvalenium hydrogen fumarate (2/1): a BEDT-TTF mixed-valency salt with a hydrogen-bonding organic anion

Michel Giffard Amédée Riou G. Mabon Nicolas Mercier P. Molinié Thien Phap Nguyen

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Abstract

Electro-oxidation of BEDT-TTF in the presence of tetrabutylammonium hydrogen fumarate affords the salt (BEDT-TTF) 2 [(E)-HO 2 C-CH=CH-CO 2 ], in which the BEDT-TTF units adopt a β-type packing and the organic anions form infinite chains by hydrogen-bonding; this salt is a semiconductor and its room-temperature conductivity is ca. 3 S cm –1 .

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Giffard et al. (1999) studied this question.

synapsesocial.com/papers/6a153075d64fa333899f587b https://doi.org/10.1039/a810002k

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