In this study, phenol adsorption from aqueous solutions was investigated using a carbonized adsorbent derived from a 1: 1: 1 mixture of banana, carrot, and potato peels, representing a major fraction of municipal bio-waste in Serbia. The material (CARBBCP) was characterized by pHpzc, SEM, FTIR, and BET analyses. The results indicated a highly porous structure with developed micro- and mesoporosity and a high specific surface area (SBET = 483 m2/g). FTIR confirmed the formation of a stable aromatic carbon structure, while the high pHpzc value (10. 55) suggested a limited role of electrostatic interactions. Adsorption experiments performed at an initial phenol concentration of 1858 mg/L, room temperature, and an adsorbent dose of 0. 1 g achieved a removal efficiency of 20. 5%. The Langmuir model provided the best fit, indicating monolayer adsorption, with good agreement between theoretical (≈187 mg/g) and experimental (≈190 mg/g) capacities. Kinetic analysis followed the pseudo-second-order model, suggesting chemisorption as the rate-controlling step. The adsorption mechanism was mainly governed by π–π interactions, hydrophobic effects, and hydrogen bonding. These results demonstrate that CARBBCP, derived from biodegradable waste, is a promising low-cost adsorbent for wastewater treatment.
Lišanin et al. (Sat,) studied this question.