. Whereas the high frequency capacitive processes can mainly be attributed to ion transport processes in the double layer, the low frequency process is ascribed to changes in the interfacial layer, including ad-/desorption and Faradaic processes. Alternative interpretations regarding the reorientation of ions, reconstruction of the metal surface and partial electron transfer between anions and Pt are considered.
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Wippermann et al. (2017) studied this question.
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