An apparatus for measuring exchange equilibria and rates of exchange of molecular deuterium with hydrogen containing compounds is described. The gas density balance is used to analyze the hydrogen-deuterium mixtures. Results on the equilibria H2+2DCl = D2+2HCl, H2+DCl = HD+HCl are reported which check the theoretical values to within the limits of the experimental errors.
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Cross et al. (1936) studied this question.
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