Magnetization dynamics in a Dy based 2D coordination network bridged by a nitronyl nitroxide radical with a CN group

Q: What does this research mean for the field?

A newly synthesized family of 2D lanthanide-radical coordination networks, specifically a Dy-based network bridged by a nitronyl nitroxide radical, exhibits distinct magnetization dynamics. Novelty: ClaimNovelty.NOVEL_FINDING. Consensus alignment: ConsensusAlignment.NEUTRAL.

Chaoyi Jin; Honghui Li; Yan Zhou; Jinkui Tang; Peng Cheng; Licun Li

doi:10.1039/d6dt00893c

January 1, 2026Dalton Transactions

Magnetization dynamics in a Dy based 2D coordination network bridged by a nitronyl nitroxide radical with a CN group

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Key Points

The aim is to investigate the magnetization dynamics of a novel coordination network incorporating Ln(III) and a nitronyl nitroxide radical.
Constructed coordination networks using Gd, Tb, and Dy with nitronyl nitroxide radicals
Analyzed magnetization dynamics and structural properties
Utilized hexafluoroacetylacetonate as a coordinating ligand
Demonstrated significant variations in magnetization dynamics across the Ln(III) series
Revealed notable interactions between the radical and the metal centers
Indicated potential applications in magnetic materials design

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Implication

Explores magnetization dynamics in a new Ln-radical network, suggesting innovative materials applications.

Abstract

A new family of Ln-radical coordination networks {[Ln(hfac)3]3(NIT-PhCN)2}n (Ln(III) = Gd 1, Tb 2 and Dy 3; hfac = hexafluoroacetylacetonate) was constructed by the reaction of NIT-PhCN nitronyl niroxide radical...

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Jin et al. (2026) studied this question.

synapsesocial.com/papers/6a17dc653fad632b0f9d91b6 https://doi.org/10.1039/d6dt00893c

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Magnetization dynamics in a Dy based 2D coordination network bridged by a nitronyl nitroxide radical with a CN group

Key Points

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Abstract

Discussion

Cite This Study

Magnetization dynamics in a Dy based 2D coordination network bridged by a nitronyl nitroxide radical with a CN group

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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