The entropies of vaporization of a number of liquids to the same vapor volume are compared and show evidence that more or less ordered arrangements in liquids can result not only from (a) chemical bonds, and (b) dipole orientation but also from (c) geometrical form. This last effect alone may suffice to cause significant departures from the entropy of forming a regular solution.
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J. H. Hildebrand (1939) studied this question.