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Wavefunctions and energies, optimized for BH3 and very nearly optimized for B2H6, have yielded a charge of −0.034 on H in BH3, and charges of −0.032 on H (terminal) and −0.001 on H (bridge) in B2H6 where the BB overlap population is 0.288.
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Palke et al. (1966) studied this question.
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