Direct Solvothermal Crystallisation of the Metastable Cubic Perovskite CsMnF ₃ and its Magnetism

Q: What does this research mean for the field?

The metastable cubic perovskite phase of CsMnF3 can be directly synthesized via solvothermal methods at a mild temperature of 100 °C, bypassing the extreme temperature and pressure conditions previously required. Novelty: ClaimNovelty.NOVEL_FINDING. Consensus alignment: ConsensusAlignment.NEUTRAL.

Craig I. Hiley; Catriona A. Crawford; Mark Senn; Richard I. Walton; Clemens Ritter

doi:10.1039/d6cc02124g

January 1, 2026Chemical CommunicationsOpen Access

Direct Solvothermal Crystallisation of the Metastable Cubic Perovskite CsMnF ₃ and its Magnetism

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Key Points

This research aims to explore a new method for synthesizing cubic CsMnF3 at lower temperatures.
Conducted solvothermal synthesis at 100 °C to achieve phase-pure cubic CsMnF3
Utilized in situ powder X-ray diffraction to analyze crystallization
Collected and analyzed data to confirm phase stability at lower conditions.
Successfully synthesized cubic CsMnF3 at 100 °C, a significant reduction from the previous 700 °C
In situ powder X-ray diffraction confirmed the phase-purity of the synthesized product

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Implication

Explores crystallization methods of cubic CsMnF3, indicating novel synthesis implications.

Abstract

The solvothermal synthesis of polycrystalline cubic CsMnF 3 at 100 °C is reported, a phase previously prepared phase-pure only at 700 °C and 30 kbar. In situ powder X-ray diffraction, shows...

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Hiley et al. (2026) studied this question.

synapsesocial.com/papers/6a192e68fab5b468c4417776 https://doi.org/10.1039/d6cc02124g

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Direct Solvothermal Crystallisation of the Metastable Cubic Perovskite CsMnF ₃ and its Magnetism

Key Points

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Implication

Abstract

Discussion

Cite This Study

Direct Solvothermal Crystallisation of the Metastable Cubic Perovskite CsMnF ₃ and its Magnetism

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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