Influence of Ice Segregation and Solutes on Soil Structural Stability

Most Canadian soils contain dissolved salts and are subject to freezing. However, the structural consequences of freezing in the presence of solutes are unknown. The effects of ice segregation and solutes on soil structural stability were investigated in a laboratory experiment. Nine 27-cm-diameter by 19-cm-high columns were used. These were packed with air-dry Conestogo silt loam soil (Gleyed Melanic Brunisol or Aquic Eutrochrept) and wetted with CaCl 2 solutions at 1, 2, and 4 g L −1 . Slow freezing took place from the top down in an environmental chamber maintained at −3.4 ± 0.4 °C. Depth of frost penetration, temperature, frost heave, and unfrozen water content were monitored within each column. After 20 d, the mean frost penetration was 107 ± 18 mm and the soil surface had heaved 9 ± 4 mm, indicating ice segregation. At the end of the experiment, the frozen and unfrozen zones of each column were sampled destructively. Samples were equilibrated at 4 °C and analyzed for wet-aggregate stability (WAS), dispersible clay (DC), gravimetric water content, and CaCl 2 concentration. Samples which had been frozen had significantly more water and CaCl 2 in the thawed state than those which had remained unfrozen. These increases were attributed to a freezing-induced redistribution of the saturating solutions. DC decreased with increasing CaCl 2 concentration, indicating an electrical double-layer effect. Soil that had been frozen and thawed had a more stable structure (in terms of both DC and WAS) than the unfrozen soil. No interaction was found between solutes and freezing. In contrast, there was a significant interaction between water content and freezing. WAS increased with decreasing water content for those aggregates which had been frozen and thawed, but not for those which had remained unfrozen. Key words: Soil structure, wet-aggregate stability, dispersible clay, frost heave, soil solution, bulk electrical conductivity