The reaction between solvent free Li{(NDippCMe)2CH} (Dipp = C6H3Pri2-2,6), ‘GaI’ and potassium in toluene afforded Ga{(NDippCMe)2CH} 1 which features a V-shaped, two-coordinate, six-electron gallium(I) center electronically analogous to a singlet carbene carbon.
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Hardman et al. (2000) studied this question.
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