Application of nonlinear magneto-optical (Faraday) rotation to magnetometry is investigated. Our experimental setup consists of a modulation polarimeter that measures rotation of the polarization plane of a laser beam resonant with transitions in Rb. Rb vapor is contained in an evacuated cell with antirelaxation coating that enables atomic ground-state polarization to survive many thousand wall collisions. This leads to ultranarrow features (~10^-6 G) in the magnetic-field dependence of optical rotation. The potential sensitivity of this scheme to sub-μG magnetic fields as a function of atomic density, light intensity, and light frequency is investigated near the $D1$ and $D2$ lines of ⁸⁵Rb. It is shown that through an appropriate choice of parameters the shot-noise-limited sensitivity to small magnetic fields can reach 3×10^-12 G/√Hz.
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Budker et al. (2000) studied this question.
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