Catalysis by the cubane-type Fe4S4 cluster has been found in metalloproteins such as biotin synthase, aconitase, and IspH, whereas some synthetic M4S4 clusters show catalytic activities for biologically related reactions or various types of organic transformations. This minireview summarizes recent progress in the chemistry of catalytic functions of cubane-type M4S4 clusters.
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Seino et al. (2011) studied this question.
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