Imidazoliumyl-Substituted Di-and Iso-Tetraphosphanes and Their Metal-Mediated Fragmentation Reactions

Jannis Fidelius; Clemens Taube; Kai Schwedtmann; Felix Hennersdorf; Rosa Maria Gomila; Antonio Frontera; Robert Wolf; Jan J. Weigand

doi:10.1039/d6sc02577c

January 1, 2026Chemical ScienceOpen Access

Imidazoliumyl-Substituted Di-and Iso-Tetraphosphanes and Their Metal-Mediated Fragmentation Reactions

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Key Points

The research aims to synthesize new imidazoliumyl-substituted phosphanes and explore their reactivity in metal-mediated fragmentation.
Synthesis of monocationic imidazoliumyl phosphanes as triflate salts.
Characterization of compounds LCP(R)Cl+ with varying substituents.
Investigation of metal-mediated reactions for fragmentation.
Successfully synthesized triflate salts 2a-c with varying R groups.
Demonstrated reactivity of these phosphanes in metal-mediated fragmentation.
Provided insights into potential applications as building blocks in coordination chemistry.

Implication

Synthesis of imidazoliumyl phosphanes demonstrates versatile building blocks for metal-mediated reactions.

Abstract

Monocationic imidazoliumyl-substituted phosphanes, LCP(R)Cl+ (LC=1,3-diisopropyl-4,5-dimethylimidazol-2-yl), were synthesized as their respective triflate salts 2a-c[OTf] (a: R = Cy; b: R = Ph; c: R = Py). These serve as versatile building...

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Cite This Study

Fidelius et al. (2026) studied this question.

synapsesocial.com/papers/6a1a82a00307b7850943450b https://doi.org/10.1039/d6sc02577c

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Imidazoliumyl-Substituted Di-and Iso-Tetraphosphanes and Their Metal-Mediated Fragmentation Reactions

Key Points

Implication

Abstract

Discussion

Cite This Study

Imidazoliumyl-Substituted Di-and Iso-Tetraphosphanes and Their Metal-Mediated Fragmentation Reactions

Key Points

Implication

Abstract

Discussion

Cite This Study

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