This paper describes a novel diamination process of terminal olefins at allylic and homoallylic carbons via formal C−H activation using di-tert-butyldiaziridinone as nitrogen source and Pd(PPh3)4 as catalyst. A wide variety of terminal olefins can be effectively diaminated in good yields with high stereoselectivity.
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Du et al. (2007) studied this question.
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