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May 31, 2026Journal of environmental chemical engineeringOpen Access

Structure-Reactivity Insights of Ozonation of Phenolic Derivatives and Efficient Valorization of Lignin into Aromatic Aldehydes

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Authors

XPXinfeng PanTRTianyu RenYHYouyang Huang

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Overview

Randomized trial explores ozonation efficiency in lignin-derived aromatic aldehydes, highlighting implications for biorefinery technologies.

Key Points

  • This research aims to understand how phenolic structure influences ozonation reactivity and to enhance lignin valorization.
  • Systematic screening of nearly 100 monomeric and dimeric phenols and their methylated analogs.
  • Analysis of ozonation effects on product yields and decomposition reactivity.
  • Evaluation of tetrahydrofurfuryl alcohol as a solvent to improve yield and minimize oxidative loss.
  • Certain phenols showed inertness to O3, while others oxidized rapidly, indicating a significant structural influence on reactivity.
  • The ozonation of para-substituted phenols followed the Hammett equation, confirming a predictable relationship between structure and reactivity.
  • High yields were achieved with methylated vanillin (88%) and methylated syringaldehyde (96%) from methylated lignin depolymerization products.

Cite This Study

Pan et al. (2026) studied this question.

synapsesocial.com/papers/6a1bd0155783ba022b6fbf36https://doi.org/10.1016/j.jece.2026.123351
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