Bridged Pincer Homodinuclear Rare-Earth Metal Complexes Catalyzed Hydrosilylation of 1-Arylsubstituted and 1,1-Disubstituted Methylenecyclopropanes with Diverse Secondary Silanes

Q: What does this research mean for the field?

Bridged pincer homodinuclear rare-earth metal complexes successfully catalyze the hydrosilylation of 1-arylsubstituted and 1,1-disubstituted methylenecyclopropanes with diverse secondary silanes. Novelty: ClaimNovelty.METHODOLOGICAL. Consensus alignment: ConsensusAlignment.NEUTRAL.

Xueqin Yan; Weigang Wang; Wenrun Yue; Mengxin Tao; Fuxiang Chai; Han Ye; Ran Zhang; Shaowu Wang

doi:10.1039/d6qo00479b

January 1, 2026Organic Chemistry Frontiers

Bridged Pincer Homodinuclear Rare-Earth Metal Complexes Catalyzed Hydrosilylation of 1-Arylsubstituted and 1,1-Disubstituted Methylenecyclopropanes with Diverse Secondary Silanes

View Full Paper

Ask AI

Bookmark

Share

Key Points

To develop an efficient catalytic method for hydrosilylation of substituted methylenecyclopropanes using rare-earth metal complexes.
Utilized bridged pincer homodinuclear rare-earth metal complexes for catalysis.
Examined hydrosilylation with diverse secondary silanes on 1-arylsubstituted and 1,1-disubstituted methylenecyclopropanes.
Analyzed reaction conditions and product yields for optimization.
Efficient hydrosilylation achieved with high yields of homoallylsilanes.
Catalysts demonstrated effectiveness with a variety of secondary silanes.
Results indicate a promising approach for synthesizing silacyclopentanes.

Implication

Catalytic process enhances hydrosilylation efficiency in methylenecyclopropanes, suggesting broad application.

Abstract

Catalytic hydrosilylation of the substituted methylenecyclopropanes is an important method for the preparation of homoallylsilanes and silacyclopentanes. However, the hydrosilylation of 1,1-disubstituted methylenecyclopropanes with secondary silanes is less developed for...

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Yan et al. (2026) studied this question.

synapsesocial.com/papers/6a1bd0525783ba022b6fc1df https://doi.org/10.1039/d6qo00479b

View Full Paper

Ask AI

Bookmark

Share

Bridged Pincer Homodinuclear Rare-Earth Metal Complexes Catalyzed Hydrosilylation of 1-Arylsubstituted and 1,1-Disubstituted Methylenecyclopropanes with Diverse Secondary Silanes

Key Points

Implication

Abstract

Discussion

Cite This Study

Bridged Pincer Homodinuclear Rare-Earth Metal Complexes Catalyzed Hydrosilylation of 1-Arylsubstituted and 1,1-Disubstituted Methylenecyclopropanes with Diverse Secondary Silanes

Key Points

Implication

Abstract

Discussion

Cite This Study

Keep reading

Keep reading