Depending on the configuration of the metal unit (cis or trans) and the sequence of coordination by six-membered heterocycles uracil, 1-methylcytosine, and 2-amino-pyridine, complexes of different topologies—open box, rectangle, or hexagon—are obtained (see below). These complexes contain six or eight metal units (with PtII, NiII, PdII, CuII, or AgI; represented by spheres) in unusual relative arrangements.
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Mutikainen et al. (1997) studied this question.
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