Polycrystalline Cu(1.8)S compounds were fabricated by using a combined process of mechanical alloying and spark plasma sintering. The Cu(1.8)S sample with a second Cu(1.96)S phase and a lot of micro pores shows its maximum ZT value 0.5 at 673 K which is the highest value for p-type sulfide thermoelectric materials so far.
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Ge et al. (2011) studied this question.
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