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We report a highly accurate ab initio study of the ionization potential (IP) and electron affinity (EA) of element 119. Electronic correlation effects are treated within the relativistic coupled-cluster theory including excitations up to quadruples. The Gaunt electron-electron interaction and QED corrections are taken into account. The role of high-order correlation effects is analyzed in detail. Our recommended values for the IP and EA are 4.7839(56) and 0.6750(71) eV, respectively. These results tighten previous estimates and provide a reference point for future experiments probing periodic-law trends beyond oganesson.
Saetgaraev et al. (Wed,) studied this question.