Rate Coefficient Measurements of the Reaction CH3 + O2 = CH3O + O

Rate coefficients for the reaction CH3 + O2 = CH3O + O were measured behind reflected shock waves in a series of lean CH4−O2−Ar mixtures using hydroxyl and methyl radical diagnostics. The rate coefficients are well represented by an Arrhenius expression given as k = (1.6 ) × 1013 exp(−15813 ± 587 K/T) cm3 mol-1 s-1. This expression, which is valid in the temperature range 1575−1822 K, supports the downward trend in the rate coefficients that has been reported in recent determinations. All measurements to date, including the present study, have been to some extent affected by secondary reactions. The complications due to secondary reactions, choice of thermochemical data, and shock−boundary layer interactions that affect the determination of the rate coefficients are examined.