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February 15, 1967The Journal of Chemical Physics514 citations

Polarizability of the Hydrogen Molecule

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WOW. Kol osLWL. Wolniewicz

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Abstract

A variation perturbation method has been employed to calculate the static dipole polarizabilities of the hydrogen molecule. The wavefunction was represented by an expansion in elliptic coordinates including the interelectronic distance. A 54-term expansion was used for the zero-order wavefunction and 34 terms for the first-order corrections. The polarizabilities computed for several values of the internuclear distance (0.4≤R≤4.0) were averaged for various vibrational and rotational states of H2, HD, and D2. The results are in a satisfactory agreement with the experimental values.

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Cite This Study

os et al. (1967) studied this question.

synapsesocial.com/papers/6a20077835281a23f90dcfd9https://doi.org/10.1063/1.1840870
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