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Topological nodal-line semimetals are characterized by one-dimensional lines of band crossing in the Brillouin zone. In contrast to nodal points, nodal lines can be in topologically nontrivial configurations. In this Rapid Communication, we introduce the concept of ``nodal-knot semimetals,'' whose nodal lines form topologically nontrivial knots in the Brillouin zone. We introduce a generic construction of nodal-knot semimetals, which yields the simplest trefoil nodal knot and other more complicated nodal knots. The knotted-unknotted transitions by nodal-line reconnections are also studied. Our work brings the knot theory to the subject of topological semimetals.
Bi et al. (Mon,) studied this question.