Porous Metal Carboxylate Boron Imidazolate Frameworks

A sponge for carbon: A new family of porous materials with tunable gas sorption properties has been prepared by integrating metal carboxylates and boron imidazolates under hydro- or solvothermal conditions. One hydrothermally synthesized phase exhibits very high volumetric CO2 storage capacity of 81 L L−1 (273 K, 1 atm). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.