Synthesis and Characterization of Titanium(iv), Vanadium(iii), Chromium(iii), and Manganese(ii) Monobromoacetates and Their Complexes With Organic Bases

Bromoacetates of the composition MX3(OOCCH2Br), MX2 (OOCCH2Br)2, MX(OOCCH2Br)3, M(OOCCH2Br)4 (M = Ti), M(OOCCH2Br)3 (M = V, Cr), M(OOCCH2Br)2 (M = Mn) and their complexes of the types MX2(OOCCH2Br)2.2B, M(OOCCH2 Br)4.2B (M = Ti, V), M(OOCCH2Br)3.B (M = Cr) and M(OOCCH2 Br)2.2B (M = Mn) (X = Cl, B = pyridine, quinoline, triethylamine or 2-fluoroaniline) have been synthesized and characterized on the basis of elemental analyses, infrared spectra, reflectance, molar conductance and magnetic susceptibility studies.