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October 2, 2015Inorganic Chemistry182 citations

Tailoring the Pore Size and Functionality of UiO-Type Metal–Organic Frameworks for Optimal Nerve Agent Destruction

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GPGregory W. PetersonSMSu‐Young MoonGWGeorge W. Wagner

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Abstract

Evaluation of UiO-66 and UiO-67 metal-organic framework derivatives as catalysts for the degradation of soman, a chemical warfare agent, showed the importance of both the linker size and functionality. The best catalysts yielded half-lives of less than 1 min. Further testing with a nerve agent simulant established that different rate-assessment techniques yield similar values for degradation half-lives.

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Peterson et al. (2015) studied this question.

synapsesocial.com/papers/6a20839c7b2df09761f89916https://doi.org/10.1021/acs.inorgchem.5b01867
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