A classical version of the Car-Parinello method is proposed, combining density-functional theory for the counterions and molecular dynamics for the macroions, to simulate charged colloidal suspensions. The classic Derjaguin-Landau-Verway-Overbeek (linear screening) theory is shown to fail for large macroion packing fractions.
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Löwen et al. (1992) studied this question.
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