Efficient Narrowband Photoconductivity of the Excitonic Resonance in Two-Dimensional Ruddlesden–Popper Perovskites Due to Exciton Polarons

Filter-less, wavelength-selective photodetectors made of perovskite usually rely on the charge collection narrowing mechanism, which intrinsically limits the response times. Using the narrow excitonic peak of, e.g., two-dimensional (2D) Ruddlesden–Popper perovskites as direct absorbers to realize color-selective photodetectivity promises faster responses. However, one major challenge in realizing such devices remains the separation and charge carrier extraction of the tightly bound excitons. Here, we report on filter-less color-selective photoconductivity in 2D perovskite butylammonium lead iodide thin film devices, exhibiting a distinct resonance in the photocurrent spectrum with a full width at half-maximum of 16.5 nm that correlates to the excitonic absorption. Our devices exhibit unexpectedly efficient charge carrier separation with an external quantum efficiency of ≤8.9% at the excitonic resonance, which we trace back to the involvement of exciton polarons. Our photodetector achieves response times of 150 μs and a maximum specific detectivity of 2.5 × 1010 Jones at the excitonic peak.