By treating the mercury atomic ion and the mercury atom as one-electron and two-electron systems respectively, and employing the Coulomb approximation to derive the atomic orbitals, the interaction energies between a Hg+ ion and a Hg atom at large nuclear separations have been calculated for the 2Σu ground state and the 2Σg repulsive state of the Hg2+ molecular ion.
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McConnell et al. (1969) studied this question.
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