The rotational magnetic moments of the diatomic alkalis have been measured by the molecular-beam magnetic-resonance method. The values obtained for the gyromagnetic ratios gJ (in nm) are: Li₂, 0.10797; Na₂, 0.03892; K₂, 0.02162; Rb₂, 0.00953; Cs₂, 0.00547. The effect of the electric quadrupole interaction on the resonance is investigated, and found to lead to a slight broadening, but, in the limit of high J, to no displacement. An interpretation of the results in terms of the irrotational-flow model used by Espe for hydrogen is given.
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Brooks et al. (1964) studied this question.
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