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Question

Accepted Answer

A highly unsaturated macrolactone undergoes transannular [6 + 4] cycloadditions to form stereoisomers of collinoketone A, demonstrating that the previously reported structure of the natural product collinoketone A must be reassigned. Novelty: ClaimNovelty.CONTRADICTORY. Consensus alignment: ConsensusAlignment.CHALLENGES_CONSENSUS.

Synthesis of Collinoketones via Biomimetic 6 + 4 Cycloaddition

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